Date of Award

2025

Document Type

Thesis

Degree Name

Master of Science (MS)

Department

Mechanical and Aerospace Engineering

Committee Chair

Robert Frederick

Committee Member

John Bennewitz

Committee Member

L. Dale Thomas

Research Advisor

Robert Frederick

Subject(s)

Solid propellants--Combustion, Ammonium perchlorate--Mechanical properties

Abstract

This thesis investigates the effect of ingredient variations on the burning rate of reduced smoke, low burning rate composite solid propellant. The effort focused on identical propellant formulations which presented significant burning rate differences correlated with the ammonium perchlorate (AP) source. A series of 1-gallon propellant mixes were prepared and tested utilizing both Manufacturer A and Manufacturer B ammonium perchlorate to investigate the propellant burning rate and pressure exponent shift anomaly and correlate those findings to the differing ingredient properties between the two AP lots. Each propellant mix was evaluated for burning rate utilizing subscale test motors and a scanning electron microscope characterized the raw AP and cast propellant surfaces. SEM images of the cast propellant surfaces showed cracking of the Manufacturer B AP indicating that the pressure exponent shift and burning rate increase observed could result from AP fracturing during propellant mixing.

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